Step 1: Write second polynomial below the first one. Making sure like terms are lined up.
$$ \begin{array}{lrrrr} & 2x^3 & & -x & 4 \\ \color{blue}{ + } & & 5x^2 & -6x & -5 \\ \hline \end{array} $$Step 2: Combine like terms (add each column):
$$ \begin{array}{lrrrr} & 2x^3 & & -x & 4 \\ \color{blue}{ + } & & 5x^2 & -6x & -5 \\ \hline & 2x^3 & 5x^2 & -7x & -1 \end{array} $$